This book arises from a NATO-sponsored Advanced Study Institute on 'The Role of Air-Sea Exchange in Geochemical Cycling' held at Bombann@§. near Bordeaux, France. from 16 to 27 September 1985. The chapters of the book are the written versions of the lectures given at the Institute. The aim of the book is to give a comprehensive up-to-date coverage of the subject. presented in a teaching mode. The chapters contain much recent research material and attempt to give the reader an understanding of how the role of air-sea exchange in geochemical cycling can be quantitatively assessed. In the last decade, major advances in the fields of marine and atmospheric chemistry have underlined the role of physical, chemical and biological processes at and near the air-sea interface in a number of geochemical cycles (C. S, N, metals etc ... ). Further, there is strong concern over the anthropogenic perturbation of these cycles on both regional and global scales. The first part of the book (Chapters 1 to 8) provides a review of topics fundamental to such studies. These topics include concepts in geochemical modelling, assessment of atmospheric transport from sources to the oceans. description of mixing and transport processes within the ocean for both dissolved and particulate materials, quantification of air-sea fluxes for both gases and particles, photochemical transformations in the atmospheric and oceanic boundary layers.

The oceans and atmosphere interact through various processes, including the transfer of momentum, heat, gases and particles. In this book leading international experts come together to provide a state-of-the-art account of these exchanges and their role in the Earth-system, with particular focus on gases and particles. Chapters in the book cover: i) the ocean-atmosphere exchange of short-lived trace gases; ii) mechanisms and models of interfacial exchange (including transfer velocity parameterisations); iii) ocean-atmosphere exchange of the greenhouse gases carbon dioxide, methane and nitrous oxide; iv) ocean atmosphere exchange of particles and v) current and future data collection and synthesis efforts. The scope of the book extends to the biogeochemical responses to emitted / deposited material and interactions and feedbacks in the wider Earth-system context. This work constitutes a highly detailed synthesis and reference; of interest to higher-level university students (Masters, PhD) and researchers in ocean-atmosphere interactions and related fields (Earth-system science, marine / atmospheric biogeochemistry / climate). Production of this book was supported and funded by the EU COST Action 735 and coordinated by the International SOLAS (Surface Ocean- Lower Atmosphere Study) project office.

The world's oceans act as a reservoir, with the capacity to absorb and retain carbon dioxide. The air-sea exchange of carbon is driven by physico-chemical forces, photosynthesis, and respiration, and has an important influence on atmospheric composition. Variability in the ocean carbon cycle could therefore exert significant feedback effects during conditions of climate change. The Joint Global Ocean Flux Study (JGOFS) is the first multidisciplinary program to directly address the interactions among the biology, chemistry, and physics of marine systems, with emphasis on the transport and transformations of carbon within the ocean and across its boundaries. This unique volume, written by an international panel of scientists, provides a synthesis of JGOFS science and its achievements to date. The authoritative chapters will be of great interest to readers seeking a current overview of the role of ocean processes in Earth system science and their wider implications for climate change.

The past two or three decades have seen many important advances in our knowledge of the chemistry, physics, geology and biology of the oceans. It has also become apparent that in order to understand the manner in which the oceans work as a 'chemical system', it is necessary to use a framework which takes account of these interdisciplinary advances. Marine geochemistry has been written in response to the need for a single state-of-the-art text that addresses the subject of treating the sea water, sediment and rock reservoirs as a unified system. In taking this approach, a process-orientated framework has been adopted in which the emphasis is placed on identifying key processes operating within the 'unified ocean'. In doing this, particular attention has been paid to making the text accessible to students from all disciplines in such a way that future advances can readily be understood. I would like to express my thanks to those people who have helped with the writing of this volume. In particular, I wish to put on record my sincere appreciation of extremely helpful suggestions made by Professor John Edmond, FRS. In addition, I thank Dr S. Rowlatt for his comments on the sections covering the geochemistry of oceanic sediments, and Dr G. Wolff for his invaluable advice on the organic geochemistry of biota, water and sediments. It is a great pleasure to acknowledge the help of Dr K. J. T.

Oceans account for 50% of the anthropogenic CO2 released into the atmosphere. During the past 15 years an international programme, the Joint Global Ocean Flux Study (JGOFS), has been studying the ocean carbon cycle to quantify and model the biological and physical processes whereby CO2 is pumped from the ocean's surface to the depths of the ocean, where it can remain for hundreds of years. This project is one of the largest multi-disciplinary studies of the oceans ever carried out and this book synthesises the results. It covers all aspects of the topic ranging from air-sea exchange with CO2, the role of physical mixing, the uptake of CO2 by marine algae, the fluxes of carbon and nitrogen through the marine food chain to the subsequent export of carbon to the depths of the ocean. Special emphasis is laid on predicting future climatic change.

Proceedings of the NATO Advanced Study Institute, Durham, New Hampshire, U.S.A., July 19-30, 1982