Demonstrating through examples, this book presents a mechanism-based perspective on the broad range of deformation and fracture response of solid polymers. It draws on the results of probing experiments and considers the similar mechanical responses of amorphous metals and inorganic compounds to develop advanced methodology for generating more precise forms of modelling. This, in turn, provides a better fundamental understanding of deformation and fracture phenomena in solid polymers. Such mechanism-based constitutive response forms have far-reaching application potential in the prediction of structural responses and in tailoring special microstructures for tough behaviour. Moreover, they can guide the development of computational codes for deformation processing of polymers at any level. Applications are wide-ranging, from large strain industrial deformation texturing to production of precision micro-fluidic devices, making this book of interest to both advanced graduate students and to practising professionals.

A physical, mechanism-based presentation of the plasticity and fracture of polymers, covering industrial scale applications through to nanoscale biofluidic devices.

This book gives an overview of recent advances in the fracture mechanics of polymers, morphology property correlations, hybrid methods for polymer testing and polymer diagnostics, and biocompatible materials and medical prostheses, as well as application examples and limits.

This book covers the most recent advances in the deformation and fracture behaviour of polymer material. It provides deeper insight into related morphology–property correlations of thermoplastics, elastomers and polymer resins. Each chapter of this book gives a comprehensive review of state-of-the-art methods of materials testing and diagnostics, tailored for plastic pipes, films and adhesive systems as well as elastomeric components and others. The investigation of deformation and fracture behaviour using the experimental methods of fracture mechanics has been the subject of intense research during the last decade. In a systematic manner, modern aspects of fracture mechanics in the industrial application of polymers for bridging basic research and industrial development are illustrated by multifarious examples of innovative materials usage. This book will be of value to scientists, engineers and in polymer materials science.

The first edition of this book had been written with the special aim to provide the necessary information for an understanding of the deformation and scission of chain molecules and its role in polymer fracture. In this field there had been an intense ac tivity in the sixties and early seventies. The new results from spectroscopical (ESR, IR) and fracture mechanics methods reported in the first edition had complemented in a very successful way the conventional interpretations of fracture behavior. The extremely friendly reception of this book by the polymer community has shown that the subject was timely chosen and that the treatment had satisfied a need. In view of the importance of a molecular interpretation of fracture phenomena and of the continued demand for this book which still is the only one of its kind, a second edition has become necessary. The aims of the second edition will be similar to those of the first: it will be at tempted to reference and evaluate completely the literature on stress-induced chain scission, now up to 1985/86. References on other subjects such as morphology, vis coelasticity, plastiC deformation and fracture mechanics, where the treatment was never meant to be exhaustive, have remained selective, but they have been updated.