The Australian Journal of Science
Title | The Australian Journal of Science PDF eBook |
Author | |
Publisher | |
Total Pages | 656 |
Release | 1969 |
Genre | Science |
ISBN |
The Australian Journal of Experimental Biology and Medical Science
Title | The Australian Journal of Experimental Biology and Medical Science PDF eBook |
Author | |
Publisher | |
Total Pages | 430 |
Release | 1924 |
Genre | Biology |
ISBN |
Australian Journal of Applied Science
Title | Australian Journal of Applied Science PDF eBook |
Author | |
Publisher | |
Total Pages | 738 |
Release | 1962 |
Genre | Agriculture |
ISBN |
The Australian Journal
Title | The Australian Journal PDF eBook |
Author | |
Publisher | |
Total Pages | 846 |
Release | 1866 |
Genre | |
ISBN |
Australian Journal of Biological Sciences
Title | Australian Journal of Biological Sciences PDF eBook |
Author | |
Publisher | |
Total Pages | 636 |
Release | 1988 |
Genre | Biology |
ISBN |
Scorpionates
Title | Scorpionates PDF eBook |
Author | Swiatoslaw Trofimenko |
Publisher | World Scientific |
Total Pages | 292 |
Release | 1999-08-16 |
Genre | Science |
ISBN | 1783261994 |
This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their “Bite” can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book. The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances. Contents: IntroductionHomoscorpionates — First GenerationHomoscorpionates — Second GenerationHeteroscorpionates, RR'BpxApplications of Scorpionate Ligands Readership: Inorganic chemists. Keywords:Scorpionaters;Polypyrazolylborates;Homoscorpionates;Heteroscorpionates;Coordination Chemistry;Catalysis;Extraction;Bioinorganic Modeling;Ligands;PyrazabolesReviews:“This important book, laden with chemical facts, is useful and well written … Exhaustive coverage of scorpionate ligands establishes this book as the definitive source for anyone considering any aspect of scorpionate chemistry.”J. Am. Chem. Soc. “This book is essential for every researcher who makes use of Tp ligands and wishes to avoid duplicating work that has already been reported.”Angew. Chem. Int. Ed.
Australian Journal of Scientific Research
Title | Australian Journal of Scientific Research PDF eBook |
Author | |
Publisher | |
Total Pages | 834 |
Release | 1952 |
Genre | Physics |
ISBN |