This innovative reference collects state-of-the-art procedures for the construction and design of nanoparticles and porous material while suggesting appropriate areas of application. Presenting both synthesis and characterization protocols, Surfaces of Nanoparticles and Porous Materials contains over 3000 references, tables, equations, drawings, and photographs. It examines the thermodynamics and kinetics of adsorption involving organic and inorganic liquids, solids, and gaseous media.. Topics include characterization, transport processes, diffusion, and the adsorption of heavy metals, ions, proteins, and pharmaceutical organics.

Porous media exist in different modern materials. It presents great surface areas with small pore size distribution. These types of materials with controllable and adjustable pore diameters are given considerable attention due to their suitable properties and applications in several fields. Porous materials have many applications in our daily life. We use different types of porous materials to clean our drinking water, for instance. This new research-oriented volume focuses on exploring the wide range of porous materials. In this new volume, original contributions from international authors along with case studies on the synthesis, design, characterization, and applications of different types of porous materials and solids are presented in detail. The book covers different types of porous materials in the broad sense by considering experimental and theoretical aspects of materials science related to porous materials and solids. The book aims to help approach characterizing a particular types of materials for more in-depth analysis. This book is divided into three parts to determine the best techniques for solving particular porous materials problems, and in each part, the fabrication and characterization of porous materials are explored with applications, describing new methodologies to gain the required information along with limitations of various methods. To make this new title a practical reference book for research students and for engineers and scientists of different disciplines working with porous materials and solids, the editors have selected a very comprehensive range of case studies as well, designed to cover the basic concepts of porosity. These case studies also describe different types of pores and surfaces for readers.

For a large number of applications involving surface interactions, there is an ever growing demand for materials with high specific surface area (surface area to volume ratio). Porous materials and nanomaterials offer higher specific surface area (SSA) each with their respective advantages and disadvantages. This research program is focused on bringing the two approaches together to create truly "hierarchical" materials that combine advantages of both while minimizing their disadvantages. In this study, various carbon based porous geometries were fabricated by grafting carbon nanotubes (CNT) onto highly porous reticulated carbon foams. These structures were further modified by functionalizing metal nanoparticles such as silver (Ag). Carbon as the base material provides desirable structural, thermal and electrical properties combined with environmental inertness. Silver nanoparticles have important anti-bacterial applications as well as future potential as sensors and electro-active devices. Mathematical models and fluid permeability tests were performed to enable comparison and adaptation of hierarchical porous structures for potential water treatment devices. Surface wettability was modified via liquid phase sol-gel method. Carbon nanotube grafted surfaces were coated with silica and influence of these coatings on surface wettability, fluid permeability, nanoparticle growth, and antibacterial efficiency were studied. Microstructure characterization of CNT grafted surfaces, silica modification, and nanoparticle deposition of these structures was studied using secondary (SE), backscatter (BE), and scanning transmission (STEM) electron microscopy. Chemical composition and surface chemistry of these structures were studied using energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) respectively. Crystallographic studies were done using X-ray diffraction (XRD) studies. Influence of CNT grafting and silica coatings on surface wettability was studied via static contact angle measurements. The anti-bacterial performance of these materials under different types of water flow configurations were tested with gram negative E. Coli K12 bacteria. Water permeability measurements of the different surface modifications on hierarchical porous structures were performed and correlated with porous structure at micro and nano scales. This study provides a comprehensive ground work for next generation functional hierarchical materials suitable for water purification devices.

Physical-Chemical Mechanics of Disperse Systems and Materials is a novel interdisciplinary area in the science of the disperse state of matter. It covers the broad spectrum of objects and systems with dimensions ranging from nanometers to millimeters and establishes a fundamental basis for controlling and tuning the properties of these systems as w

The first comprehensive textbook on the timely and rapidly developing topic of inorganic porous materials This is the first textbook to completely cover a broad range of inorganic porous materials. It introduces the reader to the development of functional porous inorganic materials, from the synthetic zeolites in the 50’s, to today’s hybrid materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and related networks. It also provides the necessary background to understand how porous materials are organized, characterized, and applied in adsorption, catalysis, and many other domains. Additionally, the book explains characterization and application from the materials scientist viewpoint, giving the reader a practical approach on the characterization and application of the respective materials. Introduction to Inorganic Porous Materials begins by describing the basic concepts of porosity and the different types of pores, surfaces, and amorphous versus crystalline materials, before introducing readers to nature’s porous materials. It then goes on to cover everything from adsorption and catalysis to amorphous materials such as silica to inorganic carbons and Periodic Mesoporous Organosilicas (PMOs). It discusses the synthesis and applications of MOFs and the broad family of COFs. It concludes with a look at future prospects and emerging trends in the field. The only complete book of its kind to cover the wide variety of inorganic and hybrid porous materials A comprehensive reference and outstanding tool for any course on inorganic porous materials, heterogeneous catalysis, and adsorption Gives students and investigators the opportunity to learn about porous materials, how to characterize them, and understand how they can be applied in different fields Introduction to Inorganic Porous Materials is an excellent book for students and professionals of inorganic chemistry and materials science with an interest in porous materials, functional inorganic materials, heterogeneous catalysis and adsorption, and solid state characterization techniques.

A state-of-the-art reference, Metal Nanoparticles offers the latest research on the synthesis, characterization, and applications of nanoparticles. Following an introduction of structural, optical, electronic, and electrochemical properties of nanoparticles, the book elaborates on nanoclusters, hyper-Raleigh scattering, nanoarrays, and several applications including single electron devices, chemical sensors, biomolecule sensors, and DNA detection. The text emphasizes how size, shape, and surface chemistry affect particle performance throughout. Topics include synthesis and formation of nanoclusters, nanosphere lithography, modeling of nanoparticle optical properties, and biomolecule sensors.

This book presents synthesis, characterization, and applications of macroporous, mesoporous, nanoporous, hierarchical porous, porous metals, and porous ceramics. Special emphasis is given to the preparation of porous activated carbon materials and porous ionic liquid-derived materials for CO2 emissions mitigation. Additionally, a chapter includes the physical and mathematical modeling in porous media. Many analytical techniques for characterization are discussed in this book. Also, the biomedical and industrial applications of porous materials in adsorption, catalysis, biosensors, drug delivery, nanotechnology are described. The content helps solving fundamental and applied problems in porous materials with length scales varying from macro- to nano-level.