Multiphase Polylactide Blends: Toward a Sustainable and Green Environment guides the reader through fundamentals, science, preparation, and key areas of innovation in polylactide (PLA) blends. Bio-based polymers, and notably PLA, have not only gained increasing interest as a more sustainable alternative but also bring challenges in terms of mechanical, rheological, thermal and physical properties, processability, shapability, and foamability. The use of blends looks to address these, with the development of new types of economically viable and environmentally friendly systems. This is a valuable book for academic researchers, scientists, and graduate students across bio-based polymers, polymer science, chemistry, and materials science, as well as engineers, R&D professionals, and all those in industry with interest in PLA-based blends, biopolymers, and sustainable materials and products. More specifically, the first three chapters of this book overview the fundamentals of thermoplastic polymers, polymer blends, and structure and properties of PLA. These chapters could technically be used as a valuable textbook on the noted topics. The rest of the chapters inclusively study the fundamentals, investigations, and achievements in PLA-based blends with various types of polymers. These include miscible blends of poly L-lactide and poly D-lactide, binary immiscible/miscible blends of PLA with other thermoplastics and elastomers, PLA-based ternary blends and blend nanocomposites, as well as PLA-based blend foams. Overall, this book provides a thorough and critical overview of the state of the art in PLA-based blends, including significant past and recent advances, with the aim of supporting and shaping further research and industrial application of these materials for the development of a green and sustainable future. Overviews the fundamentals of thermoplastic polymers, polymer blends, and the structure and properties of PLA. Provides detailed coverage of the fundamentals and science of PLA blends, including phase miscibility, thermal and mechanical properties, interface and rheological properties, the use of compatibilizers, and phase morphological analysis. Offers a thorough critical overview of the state of the art in processing and development of PLA-based blends, addressing key challenges and future perspectives. Covers the latest advances, including PLA-based ternary blends, blend nanocomposites, and PLA-based blend microcellular foams.

Sustainable Polylactide-Based Blends provides a critical overview of the state-of-the-art in polylactide (PLA)-based blends, addressing the latest advances, innovative processing techniques and fundamental issues that persist in the field. Sections cover the fundamentals of sustainable polymeric materials, polylactide and polymer blends, current and upcoming processing technologies, structure and morphology characterization techniques for PLA and PLA-based blends, and the processing, morphology development, and properties of polylactide-based blends. Final chapters focus on current and future applications, market potential, key challenges and future outlooks. Throughout the book, theoretical modeling of immiscible polymer blends helps to establish structure-property relationships in various PLA-based polymer blends. With in-depth coverage of fundamentals and processing techniques, the book aims to support the selection of each processing method, along with an understanding of surface chemistry to achieve improved compatibility between phases. Explains fundamental aspects of polylactide-based blends, including characterization methods and property measurement techniques Offers comprehensive and detailed coverage of processing, morphology and properties, all organized by blend material Analyzes novel methods and addresses challenges associated with PLA-based blends, with a focus on applications and market potential

Crystallization in Multiphase Polymer Systems is the first book that explains in depth the crystallization behavior of multiphase polymer systems. Polymeric structures are more complex in nature than other material structures due to their significant structural disorder. Most of the polymers used today are semicrystalline, and the subject of crystallization is still one of the major issues relating to the performance of semicrystalline polymers in the modern polymer industry. The study of the crystallization processes, crystalline morphologies and other phase transitions is of great significance for the understanding the structure-property relationships of these systems. Crystallization in block copolymers, miscible blends, immiscible blends, and polymer composites and nanocomposites is thoroughly discussed and represents the core coverage of this book. The book critically analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale. Various experimental techniques used for the characterization of polymer crystallization process are discussed. Written by experts in the field of polymer crystallization, this book is a unique source and enables professionals and students to understand crystallization behavior in multiphase polymer systems such as block copolymers, polymer blends, composites and nanocomposites. Covers crystallization of multiphase polymer systems, including copolymers, blends and nanocomposites Features comprehensive, detailed information about the basic research, practical applications and new developments for these polymeric materials Analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale

Biocomposites: Design and Mechanical Performance describes recent research on cost-effective ways to improve the mechanical toughness and durability of biocomposites, while also reducing their weight. Beginning with an introduction to commercially competitive natural fiber-based composites, chapters then move on to explore the mechanical properties of a wide range of biocomposite materials, including polylactic, polyethylene, polycarbonate, oil palm, natural fiber epoxy, polyhydroxyalkanoate, polyvinyl acetate, polyurethane, starch, flax, poly (propylene carbonate)-based biocomposites, and biocomposites from biodegradable polymer blends, natural fibers, and green plastics, giving the reader a deep understanding of the potential of these materials. Describes recent research to improve the mechanical properties and performance of a wide range of biocomposite materials Explores the mechanical properties of a wide range of biocomposite materials, including polylactic, polyethylene, polycarbonate, oil palm, natural fiber epoxy, polyhydroxyalkanoate, polyvinyl acetate, and polyurethane Evaluates the potential of biocomposites as substitutes for petroleum-based plastics in industries such as packaging, electronic, automotive, aerospace and construction Includes contributions from leading experts in this field

POLY(LACTIC ACID) The second edition of a key reference, fully updated to reflect new research and applications Poly(lactic acid)s – PLAs, biodegradable polymers derived from lactic acid, have become vital components of a sustainable society. Eco-friendly PLA polymers are used in numerous industrial applications ranging from packaging to medical implants and to wastewater treatment. The global PLA market is predicted to expand significantly over the next decade due to increasing demand for compostable and recyclable materials produced from renewable resources. Poly(lactic acid) Synthesis, Structures, Properties, Processing, Applications, and End of Life provides comprehensive coverage of the basic chemistry, production, and industrial use of PLA. Contributions from an international panel of experts review specific processing methods, characterization techniques, and various applications in medicine, textiles, packaging, and environmental engineering. Now in its second edition, this fully up-to-date volume features new and revised chapters on 3D printing, the mechanical and chemical recycling of PLA, PLA stereocomplex crystals, PLA composites, the environmental footprint of PLA, and more. Highlights the biodegradability, recycling, and sustainability benefits of PLA Describes processing and conversion technologies for PLA, such as injection molding, extrusion, blending, and thermoforming Covers various aspects of lactic acid/lactide monomers, including physicochemical properties and production Examines different condensation reactions and modification strategies for enhanced polymerization of PLA Discusses the thermal, rheological, and mechanical properties of PLA Addresses degradation and environmental issues of PLA, including photodegradation, radiolysis, hydrolytic degradation, biodegradation, and life cycle assessment Poly(lactic acid) Synthesis, Structures, Properties, Processing, Applications, and End of Life, Second Edition remains essential reading for polymer engineers, materials scientists, polymer chemists, chemical engineers, industry professionals using PLA, and scientists and advanced student engineers interested in biodegradable plastics.

The book summarizes in a comprehensive manner many of the recent technical research accomplishments in the area of natural polymers. It discusses the various attempts reporting on solving this problem from the point of view of the chemistry and the structure of natural polymers, highlighting the drawbacks and advantages of each method and proposal. Based on considerations of structure - property relations, it is possible to obtain fibers with improved strength by making use of their nanostructures and/or mesophase properties of natural polymers. The book is a unique book with contributions from the experts of the biomaterial area research. it covers all topics related to natural biomaterials such as natural rubber, cellulose, chitin, starch, hemicellulose, lignin, alginates, soy protein, casein and their bionanocomposites and applications. This book is a useful reference for scientists, academicians, research scholars and biotechnologists.