A knowledge of atomic theory should be an essential part of every physicist's and chemist's toolkit. This book provides an introduction to the basic ideas that govern our understanding of microscopic matter, and the essential features of atomic structure and spectra are presented in a direct and easily accessible manner. Semi-classical ideas are reviewed and an introduction to the quantum mechanics of one and two electron systems and their interaction with external electromagnetic fields is featured. Multielectron atoms are also introduced, and the key methods for calculating their properties reviewed.

The late Professor Condon and Halis Odabşi collaborate to produce an integrated account of the electron structure of atoms.

For beginners and specialists in other fields: the Nobel Laureate's introduction to atomic spectra and their relationship to atomic structures, stressing basics in a physical, rather than mathematical, treatment. 80 illustrations.

This book provides a hands-on experience with atomic structure calculations. Material covered includes angular momentum methods, the central field Schrödinger and Dirac equations, Hartree-Fock and Dirac-Hartree-Fock equations, multiplet structure, hyperfine structure, the isotope shift, dipole and multipole transitions, basic many-body perturbation theory, configuration interaction, and correlation corrections to matrix elements. The book also contains numerical methods for solving the Schrödinger and Dirac eigenvalue problems and the (Dirac)-Hartree-Fock equations.

Preface to first editionPreface to second edition1. Introduction2. The hydrogen atom- gross structure3. Radiative transitions4. The hydrogen atom- fine structure5. Two-electron system6. The central-field approximation7. Angular problems in many-electron atoms8. Interaction with static external fields9. Hyperfine structure and isotope shiftAppendix A. Some theorems of quantum mechanicsAppendix B. Results of time-independent perturbation theoryAppendix C. Notes on angular momentumAppendix D. Ground states of the elementsAppendix E. UnitsIndex

This book presents basic atomic theory as given in first and second year courses at university. It demonstrates that the structure of the Periodic Table as we know it is based on sound principles. Throughout the book, theoretical concepts are presented, along with the experimental evidence for them. Foundations are laid in the introductory chapter, which deals with fundamental particles, electromagnetic radiation and Heisenberg's uncertainty principle. Atomic orbitals are then described, using a minimum of mathematics, followed by a discussion of the electron configurations of the elements. Further chapters reveal the relationships between the electronic configurations of the elements and some properties of their atoms; and the variations in the properties of their fluorides and oxides across the periods and down the groups of the Periodic Table. Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major new series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.

Both the interpretation of atomic spectra and the application of atomic spectroscopy to current problems in astrophysics, laser physics, and thermonuclear plasmas require a thorough knowledge of the Slater-Condon theory of atomic structure and spectra. This book gathers together aspects of the theory that are widely scattered in the literature and augments them to produce a coherent set of closed-form equations suitable both for computer calculations on cases of arbitrary complexity and for hand calculations for very simple cases.