Photovoltaics, the direct conversion of sunlight to electricity, is now the fastest growing technology for electricity generation. Present "first generation" products use the same silicon wafers as in microelectronics. "Second generation" thin-films, now entering the market, have the potential to greatly improve the economics by eliminating material costs. Martin Green, one of the world’s foremost photovoltaic researchers, argues in this book that "second generation" photovoltaics will eventually reach its own material cost constraints, engendering a "third generation" of high performance thin-films. The book explores, self-consistently, the energy conversion potential of advanced approaches for improving photovoltaic performance and outlines possible implementation paths.

Photovoltaics, the direct conversion of sunlight to electricity, is now the fastest growing technology for electricity generation. Present "first generation" products use the same silicon wafers as in microelectronics. "Second generation" thin-films, now entering the market, have the potential to greatly improve the economics by eliminating material costs. Martin Green, one of the world’s foremost photovoltaic researchers, argues in this book that "second generation" photovoltaics will eventually reach its own material cost constraints, engendering a "third generation" of high performance thin-films. The book explores, self-consistently, the energy conversion potential of advanced approaches for improving photovoltaic performance and outlines possible implementation paths.

Photovoltaics, the direct conversion of sunlight to electricity, is now the fastest growing technology for electricity generation. Present "first generation" products use the same silicon wafers as in microelectronics. "Second generation" thin-films, now entering the market, have the potential to greatly improve the economics by eliminating material costs. Martin Green, one of the world’s foremost photovoltaic researchers, argues in this book that "second generation" photovoltaics will eventually reach its own material cost constraints, engendering a "third generation" of high performance thin-films. The book explores, self-consistently, the energy conversion potential of advanced approaches for improving photovoltaic performance and outlines possible implementation paths.

Photovoltaics have started replacing fossil fuels as major energy generation roadmaps, targeting higher efficiencies and/or lower costs are aggressively pursued to bring PV to cost parity with grid electricity. Third generation PV technologies may overcome the fundamental limitations of photon to electron conversion in single-junction devices and, thus, improve both their efficiency and cost. This book presents notable advances in these technologies, namely organic cells and nanostructures, dye-sensitized cells and multijunction III/V cells. The following topics are addressed: Solar spectrum conversion for photovoltaics using nanoparticles; multiscale modeling of heterojunctions in organic PV; technologies and manufacturing of OPV; life cycle assessment of OPV; new materials and architectures for dye-sensitized solar cells; advances of concentrating PV; modeling doped III/V alloys; polymeric films for lowering the cost of PV, and field performance factors. A panel of acclaimed PV professionals contributed these topics, compiling the state of knowledge for advancing this new generation of PV.

The first comprehensive book on thin-film solar cells, potentially a key technology for solving the energy production problem in the 21st century in an environmentally friendly way. It covers a wide range of scientific and technological aspects of thin film semiconductors - deposition technologies, growth mechanisms and the basic properties of amorphous and nano-crystalline silicon - as well as the optimum design theory and device physics of high-efficiency solar cells, especially of single-junction and multi-junction solar cells. The development of large-area solar cell modules using single and multi-junction solar cells is also considered. Examples of recent photovoltaic systems are presented and analysed.

Although photovoltaics are regarded by many as the most likely candidate for long term sustainable energy production, their implementation has been restricted by the high costs involved. Nevertheless, the theoretical limit on photovoltaic energy conversion efficiency-above 85%-suggests that there is room for substantial improvement of current comme

Third-generation solar cells (SCs) are built on inorganic nanoparticles, hybrids, or semiconducting organic macromolecules. This book focuses on dye-sensitized solar cells, polymer/organic solar cells, copper/zinc/tin sulfide thin film cells, quantum dot solar cells and perovskite-based solar cells. Specific topics covered include device architecture, interface engineering, characterization, and fabrication techniques such as spin coating, blade coating, slot-die coating, dip coating, meniscus coating, spray coating, ink-jet printing, screen printing and electro deposition. Keywords: Fullerene-Containing Polymers, Light-Sensitive Dye, Organic Solar Cells, Perovskite Film, Quantum Dots, Thin Film Solar Cells.