This book covers various metallurgical topics, viz. roasting of sulfide minerals, matte smelting, slag, reduction of oxides and reduction smelting, interfacial phenomena, steelmaking, secondary steelmaking, role of halides in extraction of metals, refining, hydrometallurgy and electrometallurgy. Each chapter is illustrated with appropriate examples of applications of the technique in extraction of some common, reactive, rare or refractory metal together with worked out problems explaining the principle of the operation.

This updated, second edition retains its classroom-tested treatment of physical chemistry of metallurgical topics, such as roasting of sulfide minerals, matte smelting, converting, structure, properties and theories of slag, reduction of oxides and reduction smelting, interfacial phenomena, steelmaking, secondary steelmaking, role of halides in extraction of metals, refining, hydrometallurgy and electrometallurgy, and adds new data in worked-out examples as well as up-to-date references to the literature. The book further explains the physical chemistry of various metallurgical topics, steps involved in extraction of metals, such as roasting, matte smelting/converting, reduction smelting, steelmaking reactions, deoxidation, stainless steelmaking, vacuum degassing, refining, leaching, chemical precipitation, ion exchange, solvent extraction, cementation, gaseous reduction and electrowinning. Each topic is illustrated with appropriate examples of applications of the technique in extraction of some common, reactive, rare, or refractory metal together with worked out problems explaining the principle of the operation. The problems require imagination and critical analyses and also encourage readers for creative application of thermodynamic data in metal extraction. Updates and condenses text throughout the book by sequential arrangement of paragraphs in different chapters; Maximizes readers’ understanding of the physicochemical principles involved in extraction/production of common and rare/reactive metals by pyro- as well as hydrometallurgical routes; Reinforces concepts presented with worked examples in each chapter explaining the process steps; Explains the physical chemistry of various metallurgical steps, such as roasting, matte smelting/converting, and reduction smelting, steelmaking, aqueous processing etc. in extraction of metals; Collects and uniformly presents scattered information on physicochemical principles of metal production from various books and journals.

During the last three decades, there have been dramatic changes in the steel industry in terms of the quality of products, processing technology, energy efficiency, labor productivity and environmental protection. The once prominent role of the metals industry in national economies is declining in industrialized countries to the point where fewer research engineers are employed in the industry. The scope of this book is limited to selected topics within the field of Physical Chemistry of Iron and Steelmaking"that are relevant to reduction, refining and solidification steps in the steel industry. The authors, leaders in the field, have gathered the complex information regarding metallurgy in this collection to enable the next generation to take this branch of science, and the metals industry, to new heights. Graduate students and research engineers will find this book particularly useful, while practicing engineers, innovators and managers in technology developmentwill read and consult this book for inspiration and reference.

This textbook provides a thorough and comprehensive introduction to stoichiometry and thermodynamics with special emphasis on applications to metallurgical processes. The author's approach is to introduce students early on to the fundamentals of the physical chemistry and thermodynamics of metallurgical processes and then gradually expand the treatment into progressively more advanced areas. Topics covered include the laws of thermodynamics, material and energy balances, gasification and combustion of fuels, the iron blast furnace, direct reduction reactors, nonferrous smelters, fluidized-bed roasters, the theory of solutions, chemical equilibrium, electrochemistry. Also included are over 150 worked examples and 450 exercises, many with solutions. The examples and exercises range from straightforward tests of theory to complex analyses of real processes. Every chapter is provided with a full and up-to-date set of references.

This book covers various metallurgical topics, viz. roasting of sulfide minerals, matte smelting, slag, reduction of oxides and reduction smelting, interfacial phenomena, steelmaking, secondary steelmaking, role of halides in extraction of metals, refining, hydrometallurgy and electrometallurgy. Each chapter is illustrated with appropriate examples of applications of the technique in extraction of some common, reactive, rare or refractory metal together with worked out problems explaining the principle of the operation.

Originally published in 1985, this textbook provides a thorough and comprehensive coverage of a wide range of topics in stoichiometry and thermodynamics with special emphasis on applications to metallurgical processes. This book will be welcomed as a text for courses in elementary and advanced thermodynamics and stoichiometry.